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Phenolic Resins
Ultra Low Monomer Water-Soluble Resin

Product outline

Water-soluble, low smell and low VOC phenolic resin

Ultra Low Monomer Water-Soluble Resin

Water solution of phenolic resin with <0.1% of free phenol and free formaldehyde. This resin can be dissolved in water, with quite low VOC and smell.

Technical data

樹脂特性

Grades PR-56367 PR-X22100 PR-X22127 PR-X21103 PR-X22104 PR-X22105
Type Resol Resol Resol Novolac/
hexamine
Resol Novolac
Appearance Solution Solution Solution Emulsion Solution Solution
PR-56367 PR-X22100 PR-X22127 PR-X21103 PR-X22104 PR-X22105
Free phenol (%) <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Free formaldehyde (%) <0.1 <0.1 <0.1 <0.1 <0.1 N.D.
Water solubility (times/25℃) 20< 20< 20< Emulsion 20< 20<
Viscosity (mPa·s/25℃) 70 770 30 300 4900 3500
Gelation time (sec/150℃) 50 64 61 80 85 -
Resin Content (%/135℃) 40 40 40 26 44 48
pH (-/25℃) 9.8 8.4 13.8 7.3 8.7 8.1
Fixed carbon (%/800℃) 19 15 16 13 18 18
Ash content (%/800℃) 4 0 11 0 0 0
Storage temp <10℃ <10℃ <25℃ <25℃ <10℃ <25℃

Remark

  • The value is representative.

VOC

VOC of developed resin is much lower than general resin.

VOC

Curing property

All resin can be cured at 150℃ except for PR-X22105.

Curing property

Thermal decomposition

Thermal decomposition temperature of PR-X22100 is the highest.

Thermal decomposition_1
Thermal decomposition_2

Glass-transition temperature

All resin show higher Tg than 200℃ when cured at 200℃.
Especially, Tg of PR-56367 and PR-X22100 reach over 300℃.

Glass-transition temperature_1
Glass-transition temperature_2

Physical property of resin impregnated paper

PR-X22127 has less water-durability compared to the others.
PR-X22100 and X22104 have good heat-resistance and water-durability.

Sample :  30wt% resin impregnated paper
Strength degradation against water : strength after 24hr in 80℃ water.
Strength degradation against heat : strength after 1hr at 250℃.
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