Sumitomo Bakelite Co., Ltd.
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August 28, 2001
SUMITOMO BAKELITE CO., LTD.

Development of Low Dielectric Property Materials for High Speed Signal Transfer and Multi-layer Substrate Materilas

SUMITOMO BAKELITE CO., LTD. (Headquarters: at Shinagawa ward, Tokyo, President :Tsuneo Moriya) has developed low dielectric materials " LεB SERIES" comprising a copper foil having resin thereon "APL-4901" for high frequency substrates and multiplayer substrate materials for printed circuit boards comprising thin copper clad laminate ELC-4788 and prepreg EI-6788.

Social Background
With the incoming of the "Age of High Speed Communication of Huge Amount of Information" advanced LSIs. require lower dielectric performance of printed circuit boards to meet the higher processing rate and increased number of pins. High dielectric constant will often cause noises such as cross-talks between circuit lines and the disturbance of signal wave shape with narrower and closer distance between adjacent signal lines in consequence of pursuing finer pitches. High dissipation factor on the other hand will develop big signal loss to make it impossible to maintain the original wave shape. Either of the above will cause malfunctions of LSIs. or completely hinder the proper operation of the devices. Thus, the industry really wants qualified materials for PCB with dielectric properties far superior to those of conventional materials. For substrates which require such low dielectric properties so far fluoro-plastic and special types of thermoplastic materials have been used for printed circuit boards. However, such kinds of low dielectric property materials meet difficulties in performing the same conventional processing for multi-layer substrates due to restrictions from the characteristics of such resins leaving them as rather too specific substrate materials. While, the newly offered copper foil having resin thereon for low dielectric property build-up material is a creative new product such as was not available so far. As signal transfer in the GHz frequency range is getting popularly seen not only in device packages and module substrates but also in the main boards of the base stations and switch boards of cellular phones, conventional general purpose epoxy materials (ε = 4.0-4.5, tanδ = 0.02-0.03) will sometimes cause malfunctions. Thus, we have developed the above products which meet the market needs for lower dielectric properties as well as for the convenience of processing printed circuit boards by using the same existing equipment and method for thermosetting materials.

Note: As represented in the following formula, it is preferable for materials of printed circuit boards to have low dielectric constant and low dielectric dissipation factor.

Propagation velocity=K * (C/√ε)
Propagation loss= K * (Frequency/C) * √ε * tanδ
wherein ε : dielectric constant
tanδ : dielectric dissipation factor
K : constant
C : light velocity
 
Features of recognized system materials
Two Japanese thermosetting material makers including us and another company had obtained recognition of the system(B) from UL earlier than this time and have been supplying the system materials but the systems of both companies had limitations to transformer structures and practically could not find wide use. The systems of insulating materials Class B recognized this time apparently improved the free designing allowance of transformers by increasing applicable materials and components in compliance with each transformer manufacturer's requests as wide as possible.
The materials for transformer bobbins are molding compounds "SUMIKON PM" and "SUMIKON AM " of Sumitomo Bakelite which have superior long term electrical reliability and mechanical strength. They are available in a wide line-up of grades enough to meet the rising solder temperature along with the requirement for lead free solder. We aim to expand sales of thermosetting molding materials in the transformer market by supplying this system.
* Temperature rating: Class B (130°C)
* Compatibility to various kinds of insulation: Compatible to insulation by bobbins, insulating tapes, and 3-ply insulating wires.
* Insulating tapes of various types can be used in a wide range of selection.
* Components such as insulating tubes and covers can be chosen widely.
* Bobbin materials (diallylphthalate) with CTI 600V can be used.
We forecast increasing future demand for higher temperature ratings of transformers especially in applications of industrial and communication apparatus and devices and we are simultaneously working for acquiring recognition of Class F (155°C) systems of insulating materials .
Description of the developed products
1. APL-4901 (copper foil with resin)
1. The dielectric constant of the product(ε) is 2.8 and the dissipation factor (tanδ) is 0.0025 at 1 GHz. Such much lower dielectric figures than those of conventional epoxy materials are stably exhibited in GHz ranges.
2. As for the resin, it is a heat resistant thermosetting resin having a glass transition temperature higher than 3000C.
3. The water absorption ratio is 0.2w%, which is less than 1/5 of conventional epoxy materials.
4. Halogen-free, antimony-free, and phosphorus-free :namely, an environment-friendly material.
5. In order to form a uniform insulating layer thickness the resin flow during press lamination can be controlled.

2. ELC-4788 ( Thin copper-clad laminates, for cores of multi-layer laminates) and EI-6788 (Prepreg)
1. The dielectric constant of the product(ε) at 1 GHz can be reduced from 3.5 to 3.2 by using low dielectric glass. And the dissipation factor (tanδ)is 0.0060 at 1 GHz., which is about 1/4 of conventional epoxy materials.
2. As for the resin, it is a heat resistant thermosetting resin having a glass transition temperature higher than 300°C.
3. The water absorption ratio is held about half of conventional epoxy materials.
4. Laminators can use conventional vacuum press where the same processing ability as FR-4 is exhibited.

Distinguished features of the technologies
1. APL-4901 (Copper foil with resin)
1. We started the marketing of the low dielectric property copper foil with resin which was developed for the first time in the world. The low dielectric constant of the product(ε) in the level of 2.8 and the extremely low dissipation factor (tanδ), 0.0025 both measured at 1 GHz enable to use it as a build-up material for substrates of device packages, modules for communication apparatus as well as mother boards of base stations, server substrates, etc.
2. Dependence of the dielectric properties on frequency is so small as to facilitate the application in extensive ranges of frequencies.
3. Extremely high TG coupled with extremely low water absorption ratio make itself remarkably invulnerable to environmental changes in the conditions during usage such as temperature and humidity to protect and maintain the dielectric properties.
4. Uniform thickness of the insulating layer can be secured almost regardless of the dependence of inner layer substrates on patterns by regulating the resin flow during press lamination to facilitate impedance control.

2. ELC-4788 ( Thin copper-clad laminates, for cores of multi-layer laminates) and EI-6788 (Prepreg)
1. The dielectric constant of the regular type (ε)=3.5 and that of low dielectric glass type= 3.2 both at 1 GHz are really unparalleled in this kind of highly multi-layered laminates comprising glass cloth.
2. Extremely high TG coupled with extremely low water absorption ratio make itself remarkably invulnerable to environmental changes in the conditions during usage such as temperature and humidity to protect and maintain the dielectric properties.
3. Laminators can use conventional vacuum press where the same processing ability as FR-4 is exhibited.

Patents
10 relevant patents pending.
Sales target
JPN yen 500,000,000 in 2002 as a total sum of the products herein described.

Thank you.